The 20-year-old, who entered the villa with her twin Eve Gale, put on quite the display as she attempted to flirt with Biggs, 27, on the ITV2 show last night.
Jess is currently lapping up the villa as she has two new boys desperately trying to win her over while her current coupling Mike Boateng is also enjoying getting to know the new girls in Casa Amor.
With Biggs and hunk Ched, 23, competing to get to know her, Jess got fed up with Ched interrupting her and Biggs conversations so the girls came up with a plan to district the Suffolk lad so she could get some one-on-one time with Biggs.
While the girls distracted Ched, Jess and Biggs made their way to the outside sofas and quickly got into a conversation while eating a bag of Skittles.
Attempting to impress Biggs, Jess bigged herself up that she could throw a Skittle in the air and catch it in her mouth.
Curious Biggs urged her to do the trick but sadly for Jess, it didn't quite end up how she hoped.
Throwing it into the air, the blonde bombshell leant her head back but the Skittle hilariously landed in her lashes and got caught between her false lashes.
Laughing while looking embarrassed, she quickly removed it from her face.
Viewers rushed to Twitter in hysterics to comment on the moment.
One wrote: "The awkward moment when you’re trying to flirt and get a Skittle in your lashes... happens us all," followed by a sea of laughing emojis.
A second tweeted: "This girl Jess almost blinded herself with a Skittle."
Another said: "I’m gonna watch Jess throwing a skittle into her eye forever hahahah."
Love Island continues tonight at 9pm on ITV2